The Hex Collective is at its core a duo featuring Jim Driscoll (guitar, vocals) and Josie Webber (cello, vocals), although they often work with other musicians for both recording and live projects. They play a range of material from original songs and instrumentals to some traditional folk material, and including a set of songs which consist of music written by them to words collected by the poet and railwayman Alfred Williams in the early 20th century.